DOI: 10.1615/AtoZ.p.phosphorus

Phosphorus—(Gr. phosphoros, light bearing; ancient name for the planet Venus when appealing before sunrise), P; atomic weight 30.97376; atomic number 15; melting point (white) 44.1 °C; boiling point (white) 280°C; specific gravity (white) 1.82, (red) 2.20, (black) 2.25 to 2.69; valence 3 or 5.

Discovered in 1669 by Brand, who prepared it from urine, phosphorus exists in four or more allotropic forms: white (or yellow), red, and black (or violet). White phosphorus has two modifications: α and β with a transition temperature at −3.8°C. Never found free in nature, it is widely distributed in combination with minerals. Phosphate rock, which contains the mineral apatite, an impure tri -calcium phosphate, is an important source of the element. Large deposits are found in the U.S.S.R., in Morocco, and in Florida, Tennessee, Utah, Idaho, and elsewhere. Phosphorus is an essential ingredient of all cell protoplasm, nervous tissue, and bones.

Ordinary phosphorus is a waxy white solid; when pure it is colorless and transparent. It is insoluble in water, but soluble in carbon disulfide. It takes fire spontaneously in air, burning to the pentoxide. It is very poisonous, 50 mg constituting an approximate fatal dose. Exposure to white phosphorus should not exceed 0.1 mg/M3 (8-hr time-weighted average—40-hr work week). White phosphorus should be kept under water, as it is dangerously reactive in air, and it should be handled with forceps, as contact with the skin may cause severe burns. When exposed to sunlight or when heated in its own vapor to 250°C, it is converted to the red variety, which does not phosphoresce in air as does the white variety. This form does not ignite spontaneously and it is not as dangerous as white phosphorus. It should, however, be handled with care as it does convert to the white form at some temperatures and it emits highly toxic fumes of the oxides of phosphorus when heated. The red modification is fairly stable, sublimes with a vapor pressure of 1 atm at 417°C, and is used in the manufacture of safety matches, pyrotechnics, pesticides, incendiary shells, smoke bombs, tracer bullets, etc.

White phosphorus may be made by several methods. By one process, tri-calcium phosphate, the essential ingredient of phosphate rock, is heated in the presence of carbon and silica in an electric furnace or fuel-fired blast furnace. Elementary phosphorus is liberated as vapor and may be collected under water. If desired, the phosphorus vapor and carbon monoxide produced by the reaction can be oxidized at once in the presence of moisture or water to produce phosphoric acid, an important compound in making super-phosphate fertilizers. In recent years, concentrated phosphoric acids, which may contain as much as 70 to 75% P2O5 content, have become of great importance to agriculture and farm production.

Phosphates are used in the production of special glasses, such as those used for sodium lamps. Bone-ash, calcium phosphate, is also used to produce fine china ware and mono-calcium phosphate used in baking powder. Phosphorus is also important in the production of steels, phosphor bronze, and many other products. Trisodium phosphate is important as a cleaning agent, as a water softener, and for preventing boiler scale and corrosion of pipes and boiler tubes.

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